1047680-05-6Relevant articles and documents
Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling
Waetzig, Shelli R.,Tunge, Jon A.
supporting information; experimental part, p. 3311 - 3313 (2009/02/04)
This communication details the Pd-catalyzed decarboxylation of selenocarbonates; use of a chiral nonracemic catalyst affords enantioenriched allyl selenides which undergo stereospecific [2,3]-sigmatropic rearrangements to form enantioenriched allylic amines and chlorides. The Royal Society of Chemistry.