104828-64-0Relevant articles and documents
Lewis acid-catalyzed reductive amination of carbonyl compounds with aminohydrosilanes
Miura,Ootsuka,Suda,Nishikori,Hosomi
, p. 1617 - 1619 (2007/10/03)
The TiCl4-catalyzed reaction of aromatic carbonyl compounds with (dialkylamino)dimethylsilanes gave tertiary amines in moderate to high yields. The reductive amination of aliphatic aldehydes was effectively catalyzed by ZnI2. Methyl
207. Photo-Emde Degradation of 1,2,3,4-Tetrahydroquinolinium Salts
Partali, Vassilia,Jolidon, Synese,Hansen, Hans-Juergen
, p. 1952 - 1960 (2007/10/02)
It is shown that 1,1-dimethyl-1,2,3,4-tetrahydroquinolinium ions undergo, under direct irradiation through quartz in CH3OH and independent of the nature of the counterion (I-, BF4-), a reductive cleavage of the N(1)-C(8a) bond (photo-Emde degradation).The corresponding N,N-dimethyl-3-phenylpropylamines are formed in high yields and without contamination by Hofmann degradation products of the tetrahydroquinolinium salts.Me groups at C(2) as well as substituents at C(6) (CH3, Cl, CH3O) favour the photo-Emde degradation.The aromatic Cl-substituent is reductively split off in the course of the photoreaction.