104828-68-4

Basic information

• Product Name: N,N-dimethyl-3-(3'-tolyl)propylamine
• CAS NO: 104828-68-4
• Molecular Weight: 177.29
• Mol File: 104828-68-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-dimethyl-3-(3'-tolyl)propylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-3-(3'-tolyl)propylamine(104828-68-4)
• EPA Substance Registry System: N,N-dimethyl-3-(3'-tolyl)propylamine(104828-68-4)

Safety Data

• Hazardous Substances Data: 104828-68-4(Hazardous Substances Data)

Upstream product

• 91-61-2 6-methyl-1,2,3,4 tetrahydroquinoline 
• 91-62-3 6-methylquinoline 
• 104828-74-2 1,1,6-trimethyl-1,2,3,4-tetrahydroquinolinium chloride 
• 104828-61-7 1,1,6-trimethyl-1,2,3,4-tetrahydroquinolinium iodide 

Relevant articles and documents

207. Photo-Emde Degradation of 1,2,3,4-Tetrahydroquinolinium Salts

It is shown that 1,1-dimethyl-1,2,3,4-tetrahydroquinolinium ions undergo, under direct irradiation through quartz in CH3OH and independent of the nature of the counterion (I-, BF4-), a reductive cleavage of the N(1)-C(8a) bond (photo-Emde degradation).The corresponding N,N-dimethyl-3-phenylpropylamines are formed in high yields and without contamination by Hofmann degradation products of the tetrahydroquinolinium salts.Me groups at C(2) as well as substituents at C(6) (CH3, Cl, CH3O) favour the photo-Emde degradation.The aromatic Cl-substituent is reductively split off in the course of the photoreaction.