10484-09-0

Basic information

• Product Name: ALLYL SALICYLATE
• Synonyms: 2-hydroxy-benzoicaci2-propenylester;Salicylic acid, allyl ester;ALLYL SALICYLATE;Alylsalicylate;2-Hydroxybenzoic acid allyl ester;NSC 408281
• CAS NO: 10484-09-0
• Molecular Formula: C₁₀H₁₀O₃
• Molecular Weight: 178.18
• EINECS: 233-992-0
• Product Categories: monomer
• Mol File: 10484-09-0.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 248.5℃( 760 Torr)
• Flash Point: 112.4℃
• Appearance: /
• Density: 1.158±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 0.0153mmHg at 25°C
• Refractive Index: 1.548
• PKA: 8.10±0.30(Predicted)
• CAS DataBase Reference: ALLYL SALICYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL SALICYLATE(10484-09-0)
• EPA Substance Registry System: ALLYL SALICYLATE(10484-09-0)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 10484-09-0(Hazardous Substances Data)

Usage

General Description

Allyl salicylate, also known as allyl 2-hydroxybenzoate, is an organic compound commonly used in the fragrance industry. It is derived from salicylic acid and allyl alcohol, and it emits a sweet, floral, and jasmine-like scent. Allyl salicylate is often used as a fixative in the formulation of perfumes, as well as in the production of soaps, detergents, and other personal care products. It is also used in the food industry to add fragrance and flavor to a variety of products. Despite its widespread use, allyl salicylate is a potential allergen and sensitizer, and it is subject to restrictions and regulations in some countries. Additionally,

InChI:InChI=1/C10H10O3/c1-2-7-13-10(12)8-5-3-4-6-9(8)11/h2-6,11H,1,7H2

Upstream product

• 107-18-6 allyl alcohol 
• 69-72-7 salicylic acid 
• 556-56-9 allyl iodid 
• 118-61-6 2-hydroxy-benzoic acid ethyl ester 
• 89844-08-6 prop-2-enyl 2-prop-2-enoxybenzoate 
• 106-95-6 allyl bromide 
• 64496-72-6 salicylic acid-(β,β'-dichloro-isopropyl ester) 
• 578-36-9 potassium salicylate 

Downstream Products

• 1023287-54-8 allyl 2-({3-[2-allyloxyphenyl]propanoyl}oxy)benzoate 
• 1023287-49-1 2-(allyloxycarbonyl)phenyl 2-allyloxybenzoate 
• 69-72-7 salicylic acid 
• 1406696-38-5 C₁₄H₁₄O₄ 
• 1406696-50-1 C₃₄H₄₈O₁₀Si₃ 
• 1406696-55-6 C₂₁H₃₆O₆Si₃ 

Relevant articles and documents

Derivatives of hydroxybenzoic acids and their salts: Synthesis and pharmacological activity

Preparation of salicylic and acetylsalicylic acid esters via esterification and alkylation of the salts with alkyl halides has been examined. The effect of the alkylating agent nature and the reaction conditions (catalyst and solvent) on yield of the target products has been elucidated. The biological properties of the resulting compounds can be modified by varying the nature of the alkali metal cation (K+, Na+, or Li+) of the salt form of hydroxybenzamides.

A mild and effective method for the transesterification of carboxylic acid esters

An extraordinarily versatile transesterification of simple or highly functionalized esters of aliphatic and aromatic carboxylic acids in high yields is catalyzed by dibutyltin oxide [Eq. (1)]. The reaction is compatible with several functional groups, for example, acetals, ketals, aliphatic bromides, enol ethers, urethanes, as well as free hydroxy, phenolic, and amino groups, and even with water.

A tandem Finkelstein-rearrangement-elimination reaction: a straightforward synthetic route to allyl esters

Allyl esters can be obtained by a Finkelstein-rearrangement-elimination reaction of 2-chloro-1-(chloromethyl)ethyl esters induced by NaI. Sodium iodide can be used below equivalence using a reductive agent as sodium thiosulfate. High yields are obtained with most of the diverse esters studied. The method described avoids the use of allyl alcohol as a reagent. 2-Chloro-1-(chloromethyl)ethyl esters are prepared from glycerol, the main by-product of biodiesel industry. The effectiveness of iodine as reagent to hydrolyze allyl esters is also confirmed.