1049016-50-3

Basic information

• Product Name: N-(2-pivaloyloxy-1-(4-methoxyphenyl)ethyl)-4-toluenesulfonamide
• Synonyms: N-(2-pivaloyloxy-1-(4-methoxyphenyl)ethyl)-4-toluenesulfonamide
• CAS NO: 1049016-50-3
• Molecular Weight: 405.515
• Mol File: 1049016-50-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2-pivaloyloxy-1-(4-methoxyphenyl)ethyl)-4-toluenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-pivaloyloxy-1-(4-methoxyphenyl)ethyl)-4-toluenesulfonamide(1049016-50-3)
• EPA Substance Registry System: N-(2-pivaloyloxy-1-(4-methoxyphenyl)ethyl)-4-toluenesulfonamide(1049016-50-3)

Safety Data

• Hazardous Substances Data: 1049016-50-3(Hazardous Substances Data)

Upstream product

• 53064-79-2 iodomethyl pivaloate 
• 14674-38-5 N-(4-methoxybenzylidene)-p-toluenesulfonamide 

Relevant articles and documents

Tin-free radical addition of acyloxymethyl to imines

(Chemical Equation Presented) Acyloxymethyl radicals were generated from the corresponding iodomethyl esters and successfully underwent addition to the C=N bond of N-Ts, N-PMP, and N-Dpp imines by the action of dimethylzinc or triethylborane. Ethyl acetate, toluene, and benzene as well as dichloromethane were suitable solvents. The utility of acyloxymethyl radicals as a hydroxymethyl anion equivalent was highlighted by the facile hydrolysis of the acyloxy moiety of the adducts to give the corresponding amino alcohol derivatives in good to high yield.