104933-78-0

Basic information

• Product Name: 3β-cholestanyloxy-triphenylmethyl-azothioformate
• Synonyms: 3β-cholestanyloxy-triphenylmethyl-azothioformate
• CAS NO: 104933-78-0
• Molecular Weight: 703.088
• Mol File: 104933-78-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3β-cholestanyloxy-triphenylmethyl-azothioformate(CAS DataBase Reference)
• NIST Chemistry Reference: 3β-cholestanyloxy-triphenylmethyl-azothioformate(104933-78-0)
• EPA Substance Registry System: 3β-cholestanyloxy-triphenylmethyl-azothioformate(104933-78-0)

Safety Data

• Hazardous Substances Data: 104933-78-0(Hazardous Substances Data)

Upstream product

• 76-83-5 trityl chloride 
• 5211-17-6 3β-(methylthio)thiocarbonyloxy-5α-cholestane 
• 104933-76-8 N'-Trityl-hydrazinecarbothioic acid O-[(3S,5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-yl] ester 

Downstream Products

• 481-21-0 cholestane 

Relevant articles and documents

ON THE MECHANISM OF THE DEOXYGENATION OF SECONDARY ALCOHOLS BY THE REDUCTION OF THEIR METHYL XANTHATES BY TIN HYDRIDES

Two alternate proposals for the mechanism of reduction of xanthates by tributylstannane have been examined.Evidence has been secured that under normal reduction conditions the thiocarbonyl group is attacked reversibly.At a high enough temperature the carbon radical fragments to give eventually the reduction product.Under modified conditions, where no reducing agent (Sn-H) is present, the radical formed eliminates methylthiotributylstanne and affords the thiocarbonyloxy radical observed in the e.s.r. spectrum.