104942-78-1

Basic information

• Product Name: 4,4-dimesityl-3,5,9-trioxa-4-silabicyclo<5.3.0>deca-1(10),7-diene
• CAS NO: 104942-78-1
• Molecular Weight: 392.57
• Mol File: 104942-78-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,4-dimesityl-3,5,9-trioxa-4-silabicyclo<5.3.0>deca-1(10),7-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4-dimesityl-3,5,9-trioxa-4-silabicyclo<5.3.0>deca-1(10),7-diene(104942-78-1)
• EPA Substance Registry System: 4,4-dimesityl-3,5,9-trioxa-4-silabicyclo<5.3.0>deca-1(10),7-diene(104942-78-1)

Safety Data

• Hazardous Substances Data: 104942-78-1(Hazardous Substances Data)

Upstream product

• 14496-24-3 3,4-bis(hydroxymethyl)furan 
• 5599-27-9 dichloro(dimesityl)silane 

Downstream Products

• 104942-82-7 10,10-dimesityl-2,6-bis(methoxycarbonyl)-4,9,11-trioxa-10-silapentacyclo<5.5.0.0^1,3.0^2,6.0^5,7>dodecane 
• 104942-63-4 4,4-dimesityl-11,12-bis(methoxycarbonyl)-3,5,9-trioxa-4-silabicyclo<5.3.2>dodeca-1(10),7,11-triene 
• 104942-80-5 5,5-dimesityl-10,11-bis(methoxycarbonyl)-4,6,12-trioxa-5-silatricyclo<7.2.1.0^2,8>dodeca-2(8),10-diene 

Relevant articles and documents

The Synthesis of Hetero-bridged (3,6)Oxepinophanes

The (3,6)oxepinophanes (8) are the oxepines with the shortest bridge reported so far.They were obtained starting from diethyl furan-3,4-dicarboxylate (3) which, with lithium aluminium hydride, afforded the diol (4); this was converted into the seven-membered siloxanes (5a and b) by reaction with dichlorodimethylsilane or dichlorodimesitylsilane, respectively.By the Prinzbach-Tochtermann sequence, compounds (5) were converted into the oxepinophanes (8) in three steps: Diels-Alder reaction of (5) with dimethyl acetylenedicarboxylate to give the fused 7-oxanobornadienes (6), photochemical transformations of compounds (6) to the fused 7-oxaquadricyclanes (7), and thermal isomerization of compounds (7) to (8).Attempted conversion of (8a) into (11a), a derivative of paracyclophane, was unsuccessful.