105-85-1 Usage
Description
Citronellolformate, also known as Citronellyl Formate, is a colorless liquid with a strongly fruity, rose-like odor and a sweet, fruity taste. It is characterized by its floral, waxy, fruity, citrus, and tangerine taste characteristics at 20 ppm. This versatile compound is found in various essential oils, such as geranium, Rosa borbonica, Cupressus lusitanica, mandarin, satsuma, kumquat peel oil, laurel (Laurus nobilis L.), lovage root, black currant buds, basil, and honey. Citronellolformate is combustible and soluble in most oils, with one volume dissolving in three volumes of 80% alcohol.
Uses
Used in Flavoring Industry:
Citronellolformate is used as a flavoring agent for its sweet, fruity taste and strongly fruity, rose-like odor. It is particularly suitable for enhancing the flavor of products that require a floral, waxy, fruity, citrus, or tangerine taste profile.
Used in Fragrance Industry:
Citronellolformate is used as a fragrance component for its strongly fruity, rose-like odor. It is ideal for creating fresh top notes in rose and lily of the valley fragrances, adding a unique and pleasant scent to various perfumes and scented products.
Used in Essential Oils:
Citronellolformate is used in the production of essential oils, where it contributes to the overall aroma and flavor profile. Its presence in various plant sources, such as geranium, Rosa borbonica, Cupressus lusitanica, and others, makes it a valuable component in the essential oil industry.
Used in Cosmetics and Personal Care Products:
Due to its pleasant odor and solubility properties, Citronellolformate is used in the formulation of cosmetics and personal care products, such as lotions, creams, and shampoos, to provide a fresh and fruity scent that enhances the overall sensory experience for the user.
Preparation
By direct esterification of citronellol with formic acid.
Flammability and Explosibility
Notclassified
Safety Profile
Mildly toxic by
ingestion. A human skin irritant.
Combustible liquid. When heated to
decomposition it emits acrid smoke and
irritating fumes. See also ESTERS and
FORMIC ACID.
Check Digit Verification of cas no
The CAS Registry Mumber 105-85-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 5 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 105-85:
(5*1)+(4*0)+(3*5)+(2*8)+(1*5)=41
41 % 10 = 1
So 105-85-1 is a valid CAS Registry Number.
InChI:InChI=1/C11H20O2/c1-10(2)5-4-6-11(3)7-8-13-9-12/h5,9,11H,4,6-8H2,1-3H3/t11-/m0/s1
105-85-1Relevant articles and documents
Reptilian chemistry: volatile compounds from paracloacal glands of the American crocodile (Crocodylus acutus).
Garcia-Rubio, Silvina,Attygalle, Athula B,Weldon, Paul J,Meinwald, Jerrold
, p. 769 - 781 (2002)
The secretion of the paracloacal glands of the American crocodile (Crocodylus acutus) contains over 80 lipophilic compounds, including saturated and unsaturated long-chain alcohols along with their formic, acetic, and butyric acid esters, and several isoprenoids. Most of these compounds were identified on the basis of mass spectra, obtained by GC-MS. In addition, identification of the major components was supported by infrared spectra obtained by GC-FTIR. Major differences are indicated in the composition of the paracloacal gland secretion of C. acutus and that of another crocodylid, the African dwarf crocodile (Osteolaemus tetraspis).
Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols
Chapman, Robert S.L.,Francis, Molly,Lawrence, Ruth,Tibbetts, Joshua D.,Bull, Steven D.
, p. 6442 - 6452 (2018/10/02)
Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-1-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield.
