105066-18-0

Basic information

• Product Name: benzyl trimethylsilylethynyl sulfide
• Synonyms: benzyl trimethylsilylethynyl sulfide
• CAS NO: 105066-18-0
• Molecular Weight: 220.411
• Mol File: 105066-18-0.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: benzyl trimethylsilylethynyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl trimethylsilylethynyl sulfide(105066-18-0)
• EPA Substance Registry System: benzyl trimethylsilylethynyl sulfide(105066-18-0)

Safety Data

• Hazardous Substances Data: 105066-18-0(Hazardous Substances Data)

Upstream product

• 100-53-8 phenylmethanethiol 
• 620-05-3 iodomethylbenzene 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 
• 14630-40-1 Bis(trimethylsilyl)ethyne 
• 150-60-7 dibenzyl disulphide 
• 1066-54-2 trimethylsilylacetylene 
• 75-77-4 chloro-trimethyl-silane 
• 105066-17-9 Benzyl(trichlorvinyl)sulfid 

Downstream Products

• 159497-44-6 1,4-bis(benzylthio)-1,3-butadiyne 
• 159497-47-9 (E,E)-1,4-bis(benzylthio)-1,4-diiodo-1,3-butadiene 
• 159497-49-1 (E,Z)-1,4-bis(benzylthio)-1-iodo-6-(trimethylsilyl)hexa-1,3-diene-5-yne 
• 105066-06-6 5-(Benzylsulfinyl)-2-(methylphenylamino)-3-phenylfuran 
• 105066-13-5 Benzylethinylsulfon 
• 79208-53-0 bis(benzylsulfanyl)acetylene 
• 18212-32-3 ethynylsulfanylmethylbenzene 
• 105066-19-1 Benzyl(trimethylsilylethinyl)sulfon 

Relevant articles and documents

A concise and efficient synthetic strategy to silyl-protected terminal alkynyl sulfides from alkyl or benzyl halides

A novel synthetic strategy to silyl-protected terminal alkynyl sulfides via reaction of lithium 2,2,2-tris(trimethylsilyl)ethanedithioate, produced by the reaction of tris(trimethylsilyl)methyllithium with carbon disulfide, and alkyl or benzyl halides has been developed. The scope of the reaction is broad, with a variety of benzylic and aliphatic halides and products were formed in good to excellent yields.

Metal-free C8-H functionalization of quinolineN-oxides with ynamides

The metal-free C8-H functionalization of quinolineN-oxides with ynamides is unveiled for the first time by the intramolecular Friedel-Crafts-type reaction of quinolyl enolonium intermediates generated from Br?nsted acid-catalyzed addition of quinolineN-ox

Divergent Reactivity of Thioalkynes in Lewis Acid Catalyzed Annulations with Donor–Acceptor Cyclopropanes

Efficient methods for the convergent synthesis of (poly)cyclic scaffolds are urgently needed in synthetic and medicinal chemistry. Herein, we describe new annulation reactions of thioalkynes with phthalimide-substituted donor–acceptor cyclopropanes, which gave access to highly substituted cyclopentenes and polycyclic ring systems. With silyl-thioalkynes, the Lewis acid catalyzed [3+2] annulation reaction with donor–acceptor cyclopropanes took place to afford 1-thio-cyclopenten-3-amines. On the other hand, an unprecedented polycyclic compound was formed with alkyl-thioalkynes through a reaction pathway directly involving the phthalimide group. The two transformations proceeded in good yields and tolerated a large variety of functional groups.