1051915-16-2

Basic information

• Product Name: 1-{3-[(Z)-but-1-en-1-yloxy]phenyl}ethanone
• Synonyms: 1-{3-[(Z)-but-1-en-1-yloxy]phenyl}ethanone
• CAS NO: 1051915-16-2
• Molecular Weight: 190.242
• Mol File: 1051915-16-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-{3-[(Z)-but-1-en-1-yloxy]phenyl}ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-{3-[(Z)-but-1-en-1-yloxy]phenyl}ethanone(1051915-16-2)
• EPA Substance Registry System: 1-{3-[(Z)-but-1-en-1-yloxy]phenyl}ethanone(1051915-16-2)

Safety Data

• Hazardous Substances Data: 1051915-16-2(Hazardous Substances Data)

Upstream product

• 31849-78-2 (Z)-1-bromo-1-butene 
• 121-71-1 3-Hydroxyacetophenone 

Relevant articles and documents

Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation

(Chemical Equation Presented) Highly enantioselective catalytic intramolecular ortho-alkylation of aromatic imines containing alkenyl groups tethered at the meta position relative to the imine directing group has been achieved using [RhCl(coe)2]2 and chiral phosphoramidite ligands. Cyclization of substrates containing 1,1- and 1,2-disubstituted as well as trisubstituted alkenes were achieved with enantioselectivities >90% ee for each substrate class. Cyclization of substrates with Z-alkene isomers proceeded much more efficiently than substrates with E-alkene isomers. This further enabled the highly stereoselective intramolecular alkylation of certain substrates containing Z/E-alkene mixtures via a Rh-catalyzed alkene isomerization with preferential cyclization of the Z-isomer.