1053616-65-1

Basic information

• Product Name: 2-[(2R,4S,5R)-2-Phenyl-4-((2S,4R,5S)-2-phenyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-5-trimethylsilanyloxy-[1,3]dioxan-5-yl]-thiazole
• CAS NO: 1053616-65-1
• Molecular Weight: 756.007
• Mol File: 1053616-65-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-[(2R,4S,5R)-2-Phenyl-4-((2S,4R,5S)-2-phenyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-5-trimethylsilanyloxy-[1,3]dioxan-5-yl]-thiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(2R,4S,5R)-2-Phenyl-4-((2S,4R,5S)-2-phenyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-5-trimethylsilanyloxy-[1,3]dioxan-5-yl]-thiazole(1053616-65-1)
• EPA Substance Registry System: 2-[(2R,4S,5R)-2-Phenyl-4-((2S,4R,5S)-2-phenyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-5-trimethylsilanyloxy-[1,3]dioxan-5-yl]-thiazole(1053616-65-1)

Safety Data

• Hazardous Substances Data: 1053616-65-1(Hazardous Substances Data)

Upstream product

• 79265-30-8 2-(trimethylsilyl)thiazole 
• 208039-77-4 (2R,4S)-2-Phenyl-4-((2S,4R,5S)-2-phenyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-[1,3]dioxan-5-one 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 

Downstream Products

• 208039-81-0 5-O-acetyl-(R)-2,3:(R)-4,6-di-O-benzylidene-5-C-(thiazol-2-yl)-1-O-trityl-D-glucitol 
• 208039-83-2 5-O-acetyl-(R)-2,3:(R)-4,6-di-O-benzylidene-5-C-(thiazol-2-yl)-D-glucitol 
• 208039-85-4 Acetic acid (2R,4S,5R)-4-((2R,4S,5R)-5-formyl-2-phenyl-[1,3]dioxolan-4-yl)-2-phenyl-5-thiazol-2-yl-[1,3]dioxan-5-yl ester 
• 208039-79-6 (R)-2,3:(R)-4,6-di-O-benzylidene-5-C-(thiazol-2-yl)-1-O-trityl-D-glucitol 

Relevant articles and documents

Aldehyde-Promoted Addition of 2-(Trimethylsilyl)thiazole to α,α'-Dialkoxy Ketones: A New Way to Branched-Chain Monosaccharides

The reaction of 2-(trimethylsilyl)thiazole (2-TST) with several ketones was tested in the presence or absence of aldehydes. The keto aldehyde 5 (Scheme 2) was prepared from 1 via the hydroxy aldehyde 4 in 3 steps. It reacted with 2-TST to give, after desi