105394-07-8

Basic information

• Product Name: 2-Benzenesulfonyl-2-[(3aS,5S,6aR)-5-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-hexahydro-cyclopenta[b]furan-4-yl]-1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol
• CAS NO: 105394-07-8
• Molecular Weight: 556.793
• Mol File: 105394-07-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Benzenesulfonyl-2-[(3aS,5S,6aR)-5-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-hexahydro-cyclopenta[b]furan-4-yl]-1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Benzenesulfonyl-2-[(3aS,5S,6aR)-5-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-hexahydro-cyclopenta[b]furan-4-yl]-1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol(105394-07-8)
• EPA Substance Registry System: 2-Benzenesulfonyl-2-[(3aS,5S,6aR)-5-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-hexahydro-cyclopenta[b]furan-4-yl]-1-(2,2-dimethyl-[1,3]dioxolan-4-yl)-ethanol(105394-07-8)

Safety Data

• Hazardous Substances Data: 105394-07-8(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 32233-40-2 (3aR,5R,6aS)-5-Hydroxy-4-hydroxymethyl-hexahydro-cyclopenta[b]furan-2-one 
• 105394-12-5 Toluene-4-sulfonic acid (3aS,5S,6aR)-5-hydroxy-2-oxo-hexahydro-cyclopenta[b]furan-4-ylmethyl ester 
• 105394-14-7 tert-Butyl-((3aS,5S,6aR)-2-methoxy-4-phenylsulfanylmethyl-hexahydro-cyclopenta[b]furan-5-yloxy)-dimethyl-silane 
• 105394-13-6 (3aR,5R,6aS)-2-Methoxy-4-phenylsulfanylmethyl-hexahydro-cyclopenta[b]furan-5-ol 
• 86021-69-4 (3aS,5S,6aR)-5-Hydroxy-4-phenylsulfanylmethyl-hexahydro-cyclopenta[b]furan-2-one 
• 86021-78-5 (3aS,5S,6aR)-4-Phenylsulfanylmethyl-hexahydro-cyclopenta[b]furan-2,5-diol 
• 105394-04-5 ((2S,3aS,5S,6aR)-4-Benzenesulfonylmethyl-2-methoxy-hexahydro-cyclopenta[b]furan-5-yloxy)-tert-butyl-dimethyl-silane 
• 105394-04-5 ((2R,3aS,5S,6aR)-4-Benzenesulfonylmethyl-2-methoxy-hexahydro-cyclopenta[b]furan-5-yloxy)-tert-butyl-dimethyl-silane 
• 22323-80-4 (4S)-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde 

Relevant articles and documents

A NOVEL APPROACH TO PROSTAGLANDINS FROM THE COREY LACTONE INVOLVING BF3-MEDIATED REACTIONS OF A SULPHONE AND ALDEHYDES

Transformation of the diol 1 via epimeric sulphones 7 to PGF2α is described.Alkylation of lithiated sulphones 7 with aldehydes 8a, 8b or 8c in the presence of BF3 efficiently gives corresponding adducts.