105417-09-2

Basic information

• Product Name: trifluorovinyl zinc iodide
• Synonyms: trifluorovinyl zinc iodide
• CAS NO: 105417-09-2
• Molecular Weight: 273.312
• Mol File: 105417-09-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trifluorovinyl zinc iodide(CAS DataBase Reference)
• NIST Chemistry Reference: trifluorovinyl zinc iodide(105417-09-2)
• EPA Substance Registry System: trifluorovinyl zinc iodide(105417-09-2)

Safety Data

• Hazardous Substances Data: 105417-09-2(Hazardous Substances Data)

Upstream product

• 116-14-3 polytetrafluoroethylene 
• 557-20-0 diethylzinc 
• 10377-51-2 lithium iodide 

Downstream Products

• 105436-18-8 1-isopropyl-2-(1,2,2-trifluorovinyl)benzene 
• 105417-07-0 1-Trifluoromethyl-2-trifluorovinyl-benzene 
• 82907-00-4 para-methoxy phenyl-2 trifluoro-1,1,2 ethylene 
• 104724-30-3 C₁₈H₁₄F₆O₂ 
• 105436-15-5 1-nitro-3-(1,2,2-trifluorovinyl)benzene 

Relevant articles and documents

Preparation of trifluorovinyl compounds by lithium salt-promoted monoalkylation of tetrafluoroethene

Treatment of tetrafluoroethene (TFE) with diethylzinc in the presence of lithium iodide gave 1,1,2-trifluoro-1-butene in moderate yield. In the absence of lithium iodide, however, the nucleophilic addition of diethylzinc to TFE proceeded very slowly to afford ethyl 1,1,2,2-tetrafluorobutylzinc. The addition of lithium iodide to a solution of ethyl-1,1,2,2-tetrafluorobutylzinc resulted in a smooth transformation into 1,1,2-trifluoro-1-butene. In the presence of lithium chloride, the reaction of TFE with benzyl or allyl Grignard reagents afforded the corresponding monosubstituted products in good to excellent yields.