1054612-48-4

Basic information

• Product Name: [PtCl₂(2-dicyclohexyl-phosphino-2',4',6'-triisopropylbiphenyl)2]
• CAS NO: 1054612-48-4
• Molecular Weight: 1219.44
• Mol File: 1054612-48-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [PtCl₂(2-dicyclohexyl-phosphino-2',4',6'-triisopropylbiphenyl)2](CAS DataBase Reference)
• NIST Chemistry Reference: [PtCl₂(2-dicyclohexyl-phosphino-2',4',6'-triisopropylbiphenyl)2](1054612-48-4)
• EPA Substance Registry System: [PtCl₂(2-dicyclohexyl-phosphino-2',4',6'-triisopropylbiphenyl)2](1054612-48-4)

Safety Data

• Hazardous Substances Data: 1054612-48-4(Hazardous Substances Data)

Upstream product

• 10025-65-7 platinum(II) chloride 
• 564483-18-7 XPhos 

Relevant articles and documents

Xphos ligand and platinum catalysts: A versatile catalyst for the synthesis of functionalized β-(E)-vinylsilanes from terminal alkynes

Hydrosilylation of functionalized terminal arylalkynes with a variety of silanes catalyzed by PtCl2 or PtO2 in the presence of the air-stable and bulky Xphos ligand was investigated. Regardless of the electronic nature (electron withdrawing or donating group) and the position (o, m, p) of the substituents on the aromatic ring, a single β-(E)-styrylsilanes was obtained in good to excellent yields. The regioselectivity of the H-Si bond addition was found to be governed by steric effects induced by the bulky Xphos ligand. A dramatic regioselectivity was also observed when functionalized terminal aliphatic alkynes were employed as a substrate and in these cases regioisomeric β-(E)-vinylsilanes were generated with excellent selectivity.