105465-39-2

Basic information

• Product Name: 2-(1-pyrrolidinyl)-1-tosylhexane
• Synonyms: 2-(1-pyrrolidinyl)-1-tosylhexane
• CAS NO: 105465-39-2
• Molecular Weight: 309.473
• Mol File: 105465-39-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(1-pyrrolidinyl)-1-tosylhexane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1-pyrrolidinyl)-1-tosylhexane(105465-39-2)
• EPA Substance Registry System: 2-(1-pyrrolidinyl)-1-tosylhexane(105465-39-2)

Safety Data

• Hazardous Substances Data: 105465-39-2(Hazardous Substances Data)

Upstream product

• 123-75-1 pyrrolidine 
• 71963-96-7 2-iodo-1-tosylhexane 
• 592-41-6 1-hexene 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 71964-05-1 1-tosyl-1-hexene 

Downstream Products

• 90633-60-6 1-[((E)-Hex-2-ene)-1-sulfonyl]-4-methyl-benzene 
• 105465-59-6 1-[((E)-Hept-2-ene)-2-sulfonyl]-4-methyl-benzene 
• 188430-26-4 (E)-6-propyl-6-tosyl-4-nonene 
• 188430-23-1 (E)-1-methyl-4-(non-5-en-4-ylsulfonyl)benzene 
• 105465-49-4 1-{1-[1-(Toluene-4-sulfonyl)-ethyl]-pentyl}-pyrrolidine 
• 71964-05-1 (E)-1-(hex-1-en-1-ylsulfonyl)-4-methylbenzene 

Relevant articles and documents

"Syn-Effect" in the Desulfonylation Reaction of α,α-Dialkylated (E)-Allylic Sulfones

It was found that the desulfonylation reaction of α,α-dialkylated (E)-allylic sulfones with a base preferentially affords the sterically unfavorable (Z)-alkadienes. The relative degree of the "syn-effect", which is herein defined as an effect which stabil

A CONVENIENT METHOD FOR THE PREPARATION OF α-ALKYLATED VINYLIC SULFONES AND THEIR CONVERSION TO ALLYLIC SULFONES

2-Pyrrolidinoalkyl p-tolyl sulfones, which were readily available by the addition of pyrrolidine to vinylic or allylic sulfones, were converted to the corresponding α-alkylated vinylic sulfones through α-alkylation followed by elimination of pyrrolidino g