105471-29-2

Basic information

• Product Name: [Pt(OCOC₆H₅)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]
• CAS NO: 105471-29-2
• Molecular Weight: 835.735
• Mol File: 105471-29-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pt(OCOC₆H₅)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pt(OCOC₆H₅)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)](105471-29-2)
• EPA Substance Registry System: [Pt(OCOC₆H₅)2((C₆H₅)2PCH₂CH₂P(C₆H₅)2)](105471-29-2)

Safety Data

• Hazardous Substances Data: 105471-29-2(Hazardous Substances Data)

Upstream product

• 12080-32-9 dichloro(1,5-cyclooctadiene)platinum(ll) 
• 532-31-0 silver benzoate 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Downstream Products

• 105471-30-5 C₃₈H₅₁ClP₃Pt⁽¹⁺⁾ 
• 105471-31-6 {Pt(OCOC₆H₅)(P(CH₂CH₂CH₂CH₃)3)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)}⁽¹⁺⁾ 
• 105471-32-7 [Pt(OCOC₆H₅)(P(CH₂CH₂CH₂CH₃)3)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]⁽¹⁺⁾*C₆H₅COO^(1-)=[Pt(OCOC₆H₅)(P(C₄H₉)3)(C₂H₄P₂(C₆H₅)4)](C₆H₅COO) 
• 107984-84-9 [PtCl(P(CH₂CH₂CH₂CH₃)3)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]⁽¹⁺⁾*Cl^(1-)=[PtCl(P(C₄H₉)3)(C₂H₄P₂(C₆H₅)4)]Cl 
• 105471-30-5 [PtCl(P(CH₂CH₂CH₂CH₃)3)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]⁽¹⁺⁾ 

Relevant articles and documents

Preparation and substitution reactions of (diphosphine)platinum(II) carboxylate complexes

[Pt(OCOPh)2(dppe)] (dppe = 1,2-bis(diphenylphosphino)ethane), [Pt(mal)(dppe)] (mal = malonate), and [Pt(mal)(dppm)] (dppm = bis(diphenylphosphino)methane) are prepared by treatment of [PtCl2(dppe)] or [PtCl2(dppm)] with AgOCOPh or Ag2(mal). [Pt(OCOPh)2(dppe)] reacts with P-W-Bu3 to yield [Pt(OCOPh)(P-n-Bu3)(dppe)]+, which subsequently reacts with chlorinated solvents to produce [PtCl(P-n-Bu3)(dppe)]+. Analogously, [Pt(mal)(dppe)] gives [PtCl(L)(dppe)]+ when treated with P-n-Bu3, PEt3, or PMePh2. In the case of L = P-n-Bu3 the intermediate [Pt+(OCOCH2COO-)(P-n-Bu3)(dppe)] is observed spectroscopically at low temperature and may be protonated with HClO4. The ease of substitution of dicarboxylate or diphosphine ligands is investigated by allowing [Pt(O O)(P P)] (O O = C2O4, mal; P P = dppe, dppm) to react with P-n-Bu3. [Pt(mal)(dppm)] reacts with 2 molar equiv of P-n-Bu3 or PMePh2 to give ion-paired species of the form [Pt(L)2(dppm)][mal].