10570-69-1Relevant articles and documents
": A Jack of Trio "-robust one-pot metal free oxidative amination, azidation and peroxidation of phenols
Sarkar, Debayan,Ghosh, Manoj Kumar,Rout, Nilendri,Kuila, Puspendu
supporting information, p. 3715 - 3718 (2017/07/12)
Herein we disclose a highly efficient methodology for the generation of nitrogen containing quaternary carbon centres via aminative and azidative oxidative dearomatization of phenols. The same protocol has also been successfully employed to achieve oxidative peroxidation of phenols. The simplest metal free reaction conditions delineate an easy breakthrough to the "Trio"- oxidative amination, azidation and peroxidation. An array of diverse polyfunctionalised heterocycles has been synthesized in one pot.
UNUSUAL DISPROPORTIONATION ENCOUNTERED IN THE ALUMINA-CATALYZED DEHYDRATION OF 4-(α-HYDROXYETHYL)PHENOLS
Kamogawa, Hiroyoshi,Watanabe, Motoshi,Oka, Saichiro,Nanasawa, Masato
, p. 793 - 794 (2007/10/02)
Alumina-catalyzed dehydrations of 4-(α-hydroxyethyl)phenols provided unusual disproportionation products: 4-ethylphenols and 4-acetylphenols and their tautomers.