105748-51-4

Basic information

• Product Name: Carbamic acid phenyl-thiophen-2-yl-methyl ester
• CAS NO: 105748-51-4
• Molecular Weight: 233.291
• Mol File: 105748-51-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid phenyl-thiophen-2-yl-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid phenyl-thiophen-2-yl-methyl ester(105748-51-4)
• EPA Substance Registry System: Carbamic acid phenyl-thiophen-2-yl-methyl ester(105748-51-4)

Safety Data

• Hazardous Substances Data: 105748-51-4(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 98-03-3 thiophene-2-carbaldehyde 
• 75-44-5 phosgene 
• 26059-21-2 phenyl-thiophen-2-yl-methanol 

Downstream Products

• 105748-52-5 (2-Hydroxy-1,2-diphenyl-ethyl)-carbamic acid phenyl-thiophen-2-yl-methyl ester 

Relevant articles and documents

SYNTHESES ASYMETRIQUES ET SYNTHESES ASYMETRIQUES POTENTIELLES D' α-AMINO ALCOOLS: HYDROXYAMINATION D' OLEFINES PAR LA METHODE DE SHARPLESS.

Optically active α-amino alcohols have been synthesized by Sharpless' method with (-)-10,11-dihydroquinine 2 and (R)-(-)-pantolactone 8 as chiral inducers.Five secondary (dl) alcohols : 3,4,5,6,7 and (dl) 2-hydroxyheptahelicene 1 have also been used to prepare the intermediate diastereomeric (dl) α-hydroxy carbamates 9.The highest inductions were obtained with (-)-10,11-dihydroquinine and (E)-stilbene (e.e. >/=98percent and with (dl) 2-hydroxyheptahelicene and (E)-stilbene (d.e. >/=98percent).