105930-88-9

Basic information

• Product Name: <4aR-(4aα,6α,8α,8aα)>-7,8-Bis<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>methyl>-4a,7,8,8a-tetrahydro-3-(phenylmethoxy)-1H,6H-pyrano<3,2-e><1,3,4>oxadiazine-1-carboxylic acid phenylmethyl ester
• Synonyms: <4aR-(4aα,6α,8α,8aα)>-7,8-Bis<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>methyl>-4a,7,8,8a-tetrahydro-3-(phenylmethoxy)-1H,6H-pyrano<3,2-e><1,3,4>oxadiazine-1-carboxylic acid phenylmethyl ester
• CAS NO: 105930-88-9
• Molecular Weight: 787.229
• Mol File: 105930-88-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: <4aR-(4aα,6α,8α,8aα)>-7,8-Bis<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>methyl>-4a,7,8,8a-tetrahydro-3-(phenylmethoxy)-1H,6H-pyrano<3,2-e><1,3,4>oxadiazine-1-carboxylic acid phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: <4aR-(4aα,6α,8α,8aα)>-7,8-Bis<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>methyl>-4a,7,8,8a-tetrahydro-3-(phenylmethoxy)-1H,6H-pyrano<3,2-e><1,3,4>oxadiazine-1-carboxylic acid phenylmethyl ester(105930-88-9)
• EPA Substance Registry System: <4aR-(4aα,6α,8α,8aα)>-7,8-Bis<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>methyl>-4a,7,8,8a-tetrahydro-3-(phenylmethoxy)-1H,6H-pyrano<3,2-e><1,3,4>oxadiazine-1-carboxylic acid phenylmethyl ester(105930-88-9)

Safety Data

• Hazardous Substances Data: 105930-88-9(Hazardous Substances Data)

Upstream product

• 2449-05-0 dibenzyl azodicarboxylate 
• 79999-47-6 (2R,3R,4R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,4-dihydro-2H-pyran 
• 79999-47-6 tri-O-(tert-butyldimethylsilyl)-D-glucal 
• 2449-05-0 dibenzyl azodicarboxylate 

Downstream Products

• 115828-08-5 C₃₄H₅₂N₂O₈Si₂ 
• 115828-11-0 C₄₀H₆₈N₂O₈Si₃ 
• 115828-12-1 C₄₀H₆₇⁽²⁾HN₂O₈Si₃ 
• 105930-93-6 C₄₁H₇₀N₂O₉Si₃ 
• 115828-10-9 C₄₂H₇₀N₂O₁₀Si₃ 
• 115828-09-6 C₆₇H₁₁₄N₂O₉Si₃ 
• 105930-93-6 Methyl 2-<1,2-bis<(phenylmethoxy)carbonyl>hydrazino>-2-deoxy-3,4,6-tris-O-<(1,1-dimethylethyl)dimethylsilyl>-Sb-D-glucopyranoside 
• 2771-48-4 methyl 2-acetamido-3,4,6-O-triacetyl-2-deoxy-β-D-glucopyranoside 
• 115828-05-2 C₅₂H₈₆N₂O₁₄Si₃ 

Relevant articles and documents

Cycloaddition Reaction of Dibenzyl Azodicarboxylate and Glycals

The cycloaddition reaction of dibenzyl azodicarboxylate and glycals allows the stereoselective introduction of an amino function at C-2 of a carbohydrate.Very good results were obtained with both furanoid and pyranoid glycals, except when triacetylglucal (TAG) was used as the substrate.In some instances the course of the reaction was found to be concentration dependent.

Cycloaddition of Azodicarboxylate and Glycals: A Novel and Simple Method for the Preparation of 2-Amino-2-deoxy Carbohydrates

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