105973-35-1

Basic information

• Product Name: N-(2-isopropyl-5-methylphenyl)acetamide
• Synonyms: N-(2-isopropyl-5-methylphenyl)acetamide
• CAS NO: 105973-35-1
• Molecular Weight: 191.273
• Mol File: 105973-35-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(2-isopropyl-5-methylphenyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-isopropyl-5-methylphenyl)acetamide(105973-35-1)
• EPA Substance Registry System: N-(2-isopropyl-5-methylphenyl)acetamide(105973-35-1)

Safety Data

• Hazardous Substances Data: 105973-35-1(Hazardous Substances Data)

Upstream product

• 187737-37-7 propene 
• 537-92-8 3-Methylacetanilide 
• 29685-68-5 (1R,4R,6R)-1-isopropyl-4-methyl-7-oxa-bicyclo[4.1.0]heptan-2-one 
• 127-09-3 sodium acetate 
• 108-24-7 acetic anhydride 
• 702637-77-2 (R)-4-menthen-3-one anti-oxime 
• 2437-39-0 2-isopropyl-5-methyl-phenylamine 
• 75-36-5 acetyl chloride 

Relevant articles and documents

Branch-selective alkene hydroarylation by cooperative destabilization: Iridium-catalyzed ortho-alkylation of acetanilides

An iridium(I) catalyst system, modified with the wide-bite-angle and electron-deficient bisphosphine dFppb (1,4-bis(di(pentafluorophenyl)phosphino)butane) promotes highly branch-selective hydroarylation reactions between diverse acetanilides and aryl- or alkyl-substituted alkenes. This provides direct and ortho-selective access to synthetically challenging anilines, and addresses long-standing issues associated with related Friedel-Crafts alkylations. An iridium(I) catalyst system modified with the wide-bite-angle and electron-deficient bisphosphine dFppb (1,4-bis(di(pentafluorophenyl)phosphino)butane) promotes highly branch-selective hydroarylation reactions between diverse acetanilides and aryl- or alkyl-substituted alkenes. This provides direct and ortho-selective access to synthetically challenging anilines.

(R)-4-menthen-3-one anti-oxime and its transformation under Beckman rearrangement conditions

(R)-4-Menthenone anti-oxime was synthesized for the first time. Its transformations under Beckman rearrangement conditions were studied.