106027-36-5

Basic information

• Product Name: Benzenemethanol, 4-(1,1-dimethylethyl)-a-2-propenyl-
• CAS NO: 106027-36-5
• Molecular Formula: C14H20O
• Molecular Weight: 204.312
• Mol File: 106027-36-5.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-(1,1-dimethylethyl)-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-(1,1-dimethylethyl)-a-2-propenyl-(106027-36-5)
• EPA Substance Registry System: Benzenemethanol, 4-(1,1-dimethylethyl)-a-2-propenyl-(106027-36-5)

Safety Data

• Hazardous Substances Data: 106027-36-5(Hazardous Substances Data)

Usage

Physical State

Colorless liquid

Aroma

Mild, pleasant

Source

Natural component of many essential oils

Uses

Solvent in various industries (paints, inks, coatings), preservative in pharmaceuticals, fragrance ingredient in perfumes and personal care products, flavoring agent in food and beverage industry

Properties

Antimicrobial

Safety Precautions

Can cause skin and eye irritation, use in well-ventilated areas

Upstream product

• 939-97-9 4-tert-Butylbenzaldehyde 
• 24850-33-7 allyltributylstanane 
• 1730-25-2 allylmagnesium bromide 
• 591-87-7 Allyl acetate 
• 106-95-6 allyl bromide 
• 107-18-6 allyl alcohol 
• 57699-45-3 p-tert-butoxybenzaldehyde 

Downstream Products

• 1620206-54-3 (E)-4-(4-(tert-butyl)styryl)-2-(trichloromethyl)-4,5-dihydrooxazole 
• 1620206-38-3 (E)-N-(1-bromo-4-(4-(tert-butyl)phenyl)but-3-en-2-yl)-2,2,2-trichloroacetamide 
• 1620206-20-3 C₁₆H₂₀Cl₃NO 

Relevant articles and documents

Copper-catalyzed asymmetric cyanation of alkenes via carbonyl-assisted coupling of alkyl-substituted carbon-centered radicals

Based on a copper-catalyzed radical relay strategy, the first copper-catalyzed asymmetric cyanation of alkyl-substituted alkenes has been developed. The reaction, featuring mild reaction conditions and excellent functional group compatibilities, provides

Mg(NTf2)2xH22: An efficient catalyst for the synthesis of homoallylic alcohols in water

An efficient method has been developed for the allylation of aldehydes with allytributylstannane in the presence of a catalytic amount of Mg(NTf 2)2xH22 at room temperature in water to afford the corresponding homoallylic

Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant

This paper discloses the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(iii) sulfate as the reoxidant. This methodology requires mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(iii) sulphate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcohols all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds.

Photoredox Allylation Reactions Mediated by Bismuth in Aqueous Conditions

Organometallic allylic reagents are widely used in the construction of C?C bonds by Barbier-type reactions. In this communication, we have described a photoredox Barbier allylation of aldehydes mediated by bismuth, in absence of other metals as co-reductants. Mild reaction conditions, tolerance of oxygen, and use of aqueous solvent make this photoredox methodology attractive for green and sustainable synthesis of homoallylic alcohols.