106369-05-5

Basic information

• Product Name: (3aS,6aR)-4,6-Dioxo-2-phenyl-5-p-tolyl-octahydro-pyrrolo[3,4-c]pyrrole-1-carboxylic acid methyl ester
• CAS NO: 106369-05-5
• Molecular Weight: 364.401
• Mol File: 106369-05-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3aS,6aR)-4,6-Dioxo-2-phenyl-5-p-tolyl-octahydro-pyrrolo[3,4-c]pyrrole-1-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,6aR)-4,6-Dioxo-2-phenyl-5-p-tolyl-octahydro-pyrrolo[3,4-c]pyrrole-1-carboxylic acid methyl ester(106369-05-5)
• EPA Substance Registry System: (3aS,6aR)-4,6-Dioxo-2-phenyl-5-p-tolyl-octahydro-pyrrolo[3,4-c]pyrrole-1-carboxylic acid methyl ester(106369-05-5)

Safety Data

• Hazardous Substances Data: 106369-05-5(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 1631-28-3 N-p-tolylphenylmaleimide 
• 23284-84-6 N-phenylglycine methyl ester 

Relevant articles and documents

Simple Generation of Ester-Stabilized Azomethine Ylides from 2-Amino Esters and Carbonyl Compounds. Stereochemistry of Their Cycloadditions

Condensation of 2-amino esters with carbonyl compounds leads to simple generation of ester-stabilized azomethine ylides which are trapped by olefinic dipolarophiles as cycloadducts.Anti ylides are exclusively involved in the cycloadditions when N-substituted 2-amino esters are employed for the ylide generation, while syn ylides from N-unsubstituted 2-amino esters.Relative stability among all possible ylide isomers has been inspected and the selective involvement of particular ylidic forms has been explained on the ground of 1,5-dipole interaction or hydrogen bonding stabilization.Endo- and exo-selectivity of the cycloadditions is also discussed.