106551-85-3

Basic information

• Product Name: (-)-(S,S)-1-(1-isoquinolinyl)-1-(2-pyridyl) N-(1-phenylethyl)-carbamate
• CAS NO: 106551-85-3
• Molecular Weight: 397.477
• Mol File: 106551-85-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-(S,S)-1-(1-isoquinolinyl)-1-(2-pyridyl) N-(1-phenylethyl)-carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(S,S)-1-(1-isoquinolinyl)-1-(2-pyridyl) N-(1-phenylethyl)-carbamate(106551-85-3)
• EPA Substance Registry System: (-)-(S,S)-1-(1-isoquinolinyl)-1-(2-pyridyl) N-(1-phenylethyl)-carbamate(106551-85-3)

Safety Data

• Hazardous Substances Data: 106551-85-3(Hazardous Substances Data)

Upstream product

• 55107-33-0 1-isoquinolinyl-2-pyridyl ketone 
• 1198-30-7 1-isoquinolinecarbonitrile 
• 1532-72-5 isoquinoline N-oxide 
• 17624-36-1 2-pyridyllithium 
• 14649-03-7 (-)-(S)-(α-methylbenzyl)isocyanate 
• 106551-84-2 (+/-)-1-(1-isoquinolinyl)-1-(2-pyridyl)ethanol 

Relevant articles and documents

THE SYNTHESIS OF (+)- AND (-)-1-(1-ISOQUINOLINYL)-1-(2-PYRIDYL)ETHANOL. A CHIRAL LIGAND WITH USEFUL CHELATING PROPERTIES.

(+/-)-1-(1-isoquinolinyl)-1-(2-pyridyl)ethanol has been prepared and the two enantiomers have been resolved by derivatization with a chiral isocyanate followed by a chromatographic separation.The relative configurations of the diastereomers are discussed in relation to their chromatographic behaviour and NMR spectral data.The enantiomeric alcohols obtained after hydrolysis of the diastereomeric carbamates can be alkylated or attached to a Merrifield resin to afford useful chiral chelating ligands for transition metals.