106583-99-7

Basic information

• Product Name: [Ru(Cl)(H)(CO)[P(C₆H₅)3]2[(CH₃)2C₃N₂H₂]]
• CAS NO: 106583-99-7
• Molecular Weight: 786.255
• Mol File: 106583-99-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: [Ru(Cl)(H)(CO)[P(C₆H₅)3]2[(CH₃)2C₃N₂H₂]](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(Cl)(H)(CO)[P(C₆H₅)3]2[(CH₃)2C₃N₂H₂]](106583-99-7)
• EPA Substance Registry System: [Ru(Cl)(H)(CO)[P(C₆H₅)3]2[(CH₃)2C₃N₂H₂]](106583-99-7)

Safety Data

• Hazardous Substances Data: 106583-99-7(Hazardous Substances Data)

Upstream product

• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 17567-17-8 potassium hydridotris(3,5-dimethylpyrazolyl)borate 
• 85264-33-1 1-(Hydroxymethyl)-3,5-dimethylpyrazole 
• 911716-22-8 carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) 
• 67-51-6 3,5-dimethyl-1H-pyrazole 

Downstream Products

• 115462-03-8 (Ph₃P)2(3,5-dimethylpyrazole)(CO)ClRuCHCHCOOCH₃ 
• 115462-05-0 {Ru(CO)(CH₃OOCCCHCOOCH₃)(HCO₃)(P(C₆H₅)3)2} 
• 115462-01-6 (Ph₃P)2(3,5-dimethylpyrazole)(CO)ClRuCHCHCMe₃ 
• 115462-02-7 (Ph₃P)2(3,5-dimethylpyrazole)(CO)ClRuCHCHPh 
• 115462-06-1 {Ru(NHC(C₆H₅)OCCHC₆H₅)(CO)Cl(P(C₆H₅)3)2} 
• 157931-63-0 [Ru(CO)Cl[CHCHCH₃C₆H₄][(CH₃)2C₃N₂H₂][P(C₆H₅)3]2] 
• 136626-00-1 Ru(P(C₆H₅)3)2(CO)(Cl)(C₃H₂N₂(CH₃)2)(C₂H₂C₈H₁₇) 
• 193412-09-8 Ru(P(C₆H₅)3)2(CO)(Cl)(C₃H₂N₂(CH₃)2)(C₂H₂C₆H₁₃) 
• 115462-09-4 {Ru(CO)Cl(CCC₃H₇)(3,5-dimethylpyrazole)(PPh₃)2} 

Relevant articles and documents

Synthesis of RuHCl(CO)(Hdmpz)(L)2 (L=PPh3, AsPh3, and Hdmpz=3,5-dimethylpyrazole) and crystal structure of RuHCl(CO)(Hdmpz)(AsPh3)2

Treatment of RuHCl(CO)(L)3 with a slight excess amount of K[HB(3,5-Me2pz)3] in boiling MeOH solution yielded unusual 3,5-dimethylpyrzaole (Hdmpz) complexes, RuHCl(CO)(Hdmpz)(L)2 (L=PPh3, 1 or AsPh3, 2). Unexpectedly the dissociation of the bonds between the boron atom and the nitrogen atoms of the potentially tridentate [HB(3,5-Me2pz)3]- ligand during the coordination of the ligand to the RuII metal has been observed. In a separate preparation, the RuHCl(CO)(Hdmpz)(PPh3)2 complex has also been synthesized from the reaction between RuHCl(CO)(PPh3)3 and the monodentate Hdmpz ligand. Complexes 1 and 2 have been characterized by elemental analysis, IR and 1H NMR spectroscopies. Compound 1 has also been prepared by the reaction between RuHCl(CO)(PPh3)3 and K[H2B(3,5-Me2pz)2] in boiling toluene solution. The crystal structure of 2 has been studied by X-ray crystallography. The geometrical structure around RuII of 2 is a distorted octahedral structure. The crystal structure of 2 consists of a discrete monomeric compound. It is interesting to find that the sterically-demanding [HB(3,5-Me2pz)3]- or [H2B(3,5-Me2pz)2]- ligands break up during the reaction with the RuII complexes to form the neutral 3,5-dimethylpyrazole complexes. In contrast to these observations, [H2Bpz2]- and [H2B(4-Brpz)2]- ligands form very stable RuII complexes. Elsevier Science Ltd.

Phenylacetylene dimerization promoted by ruthenium(II) complexes

The complex Ru(CO)(CH=CHPh)Cl(C5H5N)(PPh3)2 and related alkenyl complexes react in methanol or ethanol to give (E,E)-1,4-diphenylbuta-1,3-diene and the ruthenium(II) hydride Ru(CO)H(Cl)(C5H5N)(PPh3)3.Futher reaction of this hydride with the butadiene results in 1,2-reduction to yield (E)-1,4-diphenyl-1-butene.However, the reaction of phenylacetylene with catalytic amounts of ruthenium hydrides gave the dimer (Z)-1,4-diphenylbuten-3-yne.On the other hand, the reaction of 1,2-diphenylethenylruthenium(II) derivatives in methanol or ethanol gave trans-stilbene rather than the butadiene.Several deuteration experiments were performed in order to elucidate the mechanism of formation of (E,E)-1,4-diphenylbuta-1,3-diene and ruthenium hydride from the corresponding alkenyl complexes.