106631-39-4Relevant articles and documents
Pillararene-Based Two-Component Thixotropic Supramolecular Organogels: Complementarity and Multivalency as Prominent Motifs
Zafrani, Yossi,Kaizerman, Dana,Hadar, Maya,Bigan, Nitzan,Granot, Eran,Ghosh, Moumita,Adler-Abramovich, Lihi,Patolsky, Fernando,Cohen, Yoram
, p. 15750 - 15755 (2018)
Rationally designed two-component supramolecular organogels based on multiple chemical interactions between percarboxylato- and peramino-pillararenes are described. Mixing low concentration solutions (gel values in some cases exceeding the boiling point of the embedded solvent. It is demonstrated that both structural complementarity and multivalency are important determinants in the gelation process of these attractive soft materials.
The synthesis and conformation of oxygenated trianglimine macrocycles
Kuhnert, Nikolai,Lopez-Periago, Ana,Rossignolo, Giulia M.
, p. 524 - 537 (2007/10/03)
The synthesis of series of D2h and C2v symmetric oxygenated aromatic dicarboxaldehydes, using dilithiation methodology, is described along with their reactivity in the [3 + 3] cyclocondensation reaction with (1R,2R)-diaminocyclohexane to give oxygenated trianglimine macrocycles. Macrocycles derived from C2v symmetric dialdehydes give macrocycles with a stereogenic aromatic plane with complete diastereocontrol, as a mixture of retainers.