106649-35-8

Basic information

• Product Name: Methanol, [bis(4-methoxyphenyl)phosphinyl]-
• CAS NO: 106649-35-8
• Molecular Formula: C15H17O4P
• Molecular Weight: 292.271
• Mol File: 106649-35-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Methanol, [bis(4-methoxyphenyl)phosphinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanol, [bis(4-methoxyphenyl)phosphinyl]-(106649-35-8)
• EPA Substance Registry System: Methanol, [bis(4-methoxyphenyl)phosphinyl]-(106649-35-8)

Safety Data

• Hazardous Substances Data: 106649-35-8(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 15754-51-5 bis(4-methoxyphenyl)phosphine oxide 

Downstream Products

• 13685-40-0 C₁₅H₁₆ClO₃P 

Relevant articles and documents

Reduction of functionalized tertiary phosphine oxides with BH3

A direct stereoselective conversion of tertiary hydroxyalkylphosphine oxides to the corresponding tertiary hydroxyalkylphosphine-boranes involving facile reduction of the P=O bond by BH3 under mild conditions has been developed. The unprecedented facility of reduction of the strong P=O bond by BH3, a mild reducing agent, has been achieved through an intramolecular P=O···B complexation directed by proximal aα- or β-hydroxy groups present in the phosphine oxide structures. As established by two chemical correlations, the developed transformation of hydroxyalkylphosphine oxides into hydroxyalkylphosphine-boranes takes place with complete inversion of configuration at P.

RELATIONSHIPS OF ROTATIONAL ISOMERISM IN METHYL-SUBSTITUTED DIALKYL- AND DIARYLMETHYLPHOSPHINE OXIDES

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