106708-08-1

Basic information

• Product Name: (E)-2-octenyl p-toluenesulfinate
• Synonyms: (E)-2-octenyl p-toluenesulfinate
• CAS NO: 106708-08-1
• Molecular Weight: 266.404
• Mol File: 106708-08-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-2-octenyl p-toluenesulfinate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-octenyl p-toluenesulfinate(106708-08-1)
• EPA Substance Registry System: (E)-2-octenyl p-toluenesulfinate(106708-08-1)

Safety Data

• Hazardous Substances Data: 106708-08-1(Hazardous Substances Data)

Upstream product

• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 18409-17-1 (E)-oct-2-en-1-ol 

Downstream Products

• 89268-74-6 1-methyl-4-(oct-1-en-3-ylsulfonyl)benzene 
• 89268-73-5 1-methyl-4-(oct-1-en-3-ylsulfonyl)benzene 
• 100696-60-4 (E)-2-octenyl p-tolyl sulfone 
• 79243-02-0 1-methyl-4-(oct-1-en-3-ylsulfonyl)benzene 
• 90633-61-7 1-Methyl-4-[((E)-oct-2-ene)-1-sulfonyl]-benzene 

Relevant articles and documents

Palladium-Catalyzed Allylic Sulfinate-Sulfone Rearrangements

Upon treatment with a zero-valent palladium catalyst, tetrakis(triphenylphosphine)palladium, in tetrahydrofuran under mild conditions allylic p-toluenesulfinates underwent α- or γ-rearrangements of the sulfonyl group via ionic intermediates to give allylic sulfones.The regiochemistry of the rearrangements depends on the character of the intermediary allylic cationic carbons generated and the steric hindrance involved therein.Keywords - allylic sulfinate; allylic sulfone; palladium catalyst; sulfinate-sulfone rearrangement; regiochemistry; tetrakis(triphenylphosphine)palladium.