1068439-08-6

Basic information

• Product Name: [(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]benzene
• Synonyms: [(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]benzene
• CAS NO: 1068439-08-6
• Molecular Weight: 306.411
• Mol File: 1068439-08-6.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: [(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]benzene(1068439-08-6)
• EPA Substance Registry System: [(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]benzene(1068439-08-6)

Safety Data

• Hazardous Substances Data: 1068439-08-6(Hazardous Substances Data)

Upstream product

• 4073-59-0 bis-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinan-2-yl)disulfide 
• 934751-37-8 (5,5-dimethyl-2-thiono-1,3,2-dioxophosphorinanyl) sulfenyl bromide 
• 108-98-5 thiophenol 
• 934499-56-6 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 697-45-0 5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane 

Downstream Products

• 95914-29-7 1-(4-methoxyphenyl)-2-phenyldisulfane 
• 63116-23-4 4-(phenyldisulfanyl)phenol 
• 29627-34-7 4-(phenyldisulfanyl)toluene 
• 20168-72-3 4-nitrophenyl phenyl disulfide 
• 23853-95-4 1-(naphthalen-2-yl)-2-phenyldisulfane 
• 1262447-21-1 (dodec-1-yl-trisulfanyl)benzene 
• 23847-33-8 N-benzoylbenzenesulfenamide 
• 882-33-7 diphenyldisulfane 
• 68556-50-3 N-(phenylthio)trimethylacetamide 
• 4237-00-7 thiophosphoric acid O,O'-dimethyl ester S-phenyl ester 

Relevant articles and documents

Efficient synthesis of functionalized unsymmetrical dialkyl trisulfanes

We have developed a convenient method for the synthesis of functionalized unsymmetrical dialkyl trisulfanes under mild conditions in very good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2- dioxaphosphorinan-2-yl)-di

A convenient method for the preparation of functionalized N-acylsulfenamides from primary amides

We have developed a convenient method for the synthesis of functionalized N-acylsulfenamides under mild conditions and in moderate to good yields. The designed method is based on the reaction of (5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)-disulfanyl derivatives with nitrogen nucleophiles generated from primary amides or imides and sodium hydride. The developed method allows for the preparation of N-acylsulfenamides bearing additional hydroxyl, carboxyl, or amino functionalities.

DDQ-mediated synthesis of functionalized unsymmetrical disulfanes

We developed a simple and efficient method for the synthesis of functionalized unsymmetrical disulfanes under mild conditions in good yields. The designed method is based on the reaction of bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfane with thiols in the presence of 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). The developed method allows the preparation of unsymmetrical disulfanes bearing additional hydroxy, carboxy, or amino functionalities.