1068459-73-3Relevant articles and documents
A facile one-pot synthesis of a?-halo-a?-allyl-aldehydes from a?,a?-Dihaloketoncs Using Allylsamarium Bromide and DMF
Di, Jucai,Zhang, Songlin
, p. 1491 - 1494 (2008)
A convenient, one-pot synthesis of a range of a?-halo-a?-allyl aldehydes is described. The protocol involves the reaction of allylsamarium bromide with various a?,a?-dihalo ketones. A possible mechanism of the transformation is proposed.
A facile synthesis of two series of multifunctional carbon compounds from α,α-dihalo ketones using allylsamarium bromide
Liu, Xiaodan,Zhang, Songlin,Di, Jucai
experimental part, p. 2749 - 2755 (2010/01/21)
The use of allylsamarium bromide to effect two different reactions on the common starting material, a,a-dihalo ketones, is presented. With DMF, α-halo-α-allyl aldehydes were obtained, while α-hydroxy- α-allyl aldehyde acetals were obtained in the presence of NaOMe/MeOH. Georg Thieme Verlag Stuttgart.