1069130-26-2Relevant articles and documents
Stereoselective Traceless Borylation–Allenation of Propargylic Epoxides: Dual Role of the Copper Catalyst
Jarava-Barrera, Carlos,Parra, Alejandro,Amenós, Laura,Arroyo, Ana,Tortosa, Mariola
supporting information, p. 17478 - 17481 (2017/11/30)
Chiral α-allenols are prepared with high diastereocontrol through an unprecedented and spontaneous β-oxygen elimination of an α-epoxy vinyl boronate. Stochiometric experiments and DFT calculations support a dual role of the copper catalyst, which orchestrates the hydroboration and the syn-elimination step.
Dual role of alkynyl halides in one-step synthesis of alkynyl epoxides
Trofimov, Alexander,Chernyak, Natalia,Gevorgyan, Vladimir
supporting information; experimental part, p. 13538 - 13539 (2009/02/06)
It was demonstrated that alkynyl halides could serve as a source of Br+ and acetylide ions in the same transformation. This allowed for the efficient one-step preparation of alkynyl epoxides, important organic building blocks, from readily available starting materials. Copyright