106930-04-5Relevant articles and documents
A Concise and Stereoselective Route to the Predominant Stereochemical Pattern of the Tetrahydropyranoid Antibiotics: An Application to Indanomycin
Danishefsky, Samuel J.,DeNinno, Shari,Lartey, Paul
, p. 2082 - 2089 (2007/10/02)
The reactions of (E)- and (Z)-crotylsilanes of the type R3Si-CH2-CH=CH-CH3 with activated glycal derivatives in the presence of BF3 etherate have been examined.In all cases, the reactions were regiospecific, resulting in incorporation of a 3-methylprop-1-