1071035-30-7

Basic information

• Product Name: Phosphoric acid 1-cyano-5-isopropenyl-2-methyl-cyclohex-2-enyl ester diethyl ester
• Synonyms: Phosphoric acid 1-cyano-5-isopropenyl-2-methyl-cyclohex-2-enyl ester diethyl ester
• CAS NO: 1071035-30-7
• Molecular Weight: 313.334
• Mol File: 1071035-30-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphoric acid 1-cyano-5-isopropenyl-2-methyl-cyclohex-2-enyl ester diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric acid 1-cyano-5-isopropenyl-2-methyl-cyclohex-2-enyl ester diethyl ester(1071035-30-7)
• EPA Substance Registry System: Phosphoric acid 1-cyano-5-isopropenyl-2-methyl-cyclohex-2-enyl ester diethyl ester(1071035-30-7)

Safety Data

• Hazardous Substances Data: 1071035-30-7(Hazardous Substances Data)

Upstream product

• 99-49-0 Carvone 
• 2942-58-7 diethyl cyanophosphonate 
• 2408-36-8 lithium cyanide 
• 2244-16-8 (-)-Carvone 

Downstream Products

• 93378-82-6 2-methyl-5-(1-methylethenyl)cyclohex-2-enecarbonitrile 
• 138-86-3 (S)-(-)-limonene 

Relevant articles and documents

Cyano Phosphate: An Efficient Intermediate for the Chemoselective Conversion of Carbonyl Compounds to Nitriles

Cyanohydrin diethyl phosphates, readily obtained from various ketones and aldehydes by reaction with diethyl phosphorocyanidate and lithium cyanide, reacted chemoselectively with samarium(II) iodide in THF to give the corresponding nitriles in excellent yields.This method was also found applicable to α,β-unsaturated carbonyl compounds via cyano phosphates to give β,γ-unsaturated nitriles, not obtainable by standard methods, without isomerization of the double bonds.

CYANOPHOSPHATE: AN EFFICIENT INTERMEDIATE FOR CONVERSION OF CARBONYL COMPOUNDS TO NITRILES

A novel and high yield conversion of saturated or unsaturated carbonyl compounds to nitriles via cyanophosphates by samarium diiodide in the presence of tert-butanol is described.