107164-18-1Relevant articles and documents
A Convenient One-pot Synthesis of Unsymmetrical Selenium Compounds Using Bis(trimethylsilyl) Selenide
Segi, Masahito,Kato, Masakazu,Nakajima, Tadashi,Suga, Sohei,Sonoda, Noboru
, p. 1009 - 1012 (2007/10/02)
The reaction of bis(trimethylsilyl) selenide with n-BuLi followed by alkylation with an R1X gave alkyl silyl selenides.The repetition of a similar one-pot operation with the second n-BuLi and R2X yielded unsymmetrical selenides (R1SeR2) in good yields.This one-pot procedure could be also applicable to the syntheses of selenolesters, selenolcarbonates, and a phosphinothioyl selenide.
