1072440-23-3

Basic information

• Product Name: (3S,4R,5S,6R)-4,5,7-tris(benzyloxy)-6-(tert-butyldimethylsilyloxy)hept-1-en-3-ol
• Synonyms: (3S,4R,5S,6R)-4,5,7-tris(benzyloxy)-6-(tert-butyldimethylsilyloxy)hept-1-en-3-ol
• CAS NO: 1072440-23-3
• Molecular Weight: 562.822
• Mol File: 1072440-23-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4R,5S,6R)-4,5,7-tris(benzyloxy)-6-(tert-butyldimethylsilyloxy)hept-1-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R,5S,6R)-4,5,7-tris(benzyloxy)-6-(tert-butyldimethylsilyloxy)hept-1-en-3-ol(1072440-23-3)
• EPA Substance Registry System: (3S,4R,5S,6R)-4,5,7-tris(benzyloxy)-6-(tert-butyldimethylsilyloxy)hept-1-en-3-ol(1072440-23-3)

Safety Data

• Hazardous Substances Data: 1072440-23-3(Hazardous Substances Data)

Upstream product

• 1119-22-8 divinyl zinc 
• 78009-77-5 2,3,5-tri-O-benzyl-4-O-(tert-butyldimethylsilyl)-aldehydo-D-arabinose 

Downstream Products

• 93125-77-0 (2R,3R,4R,5S)-1,3,4-tris(benzyloxy)hept-6-ene-2,5-diol 

Relevant articles and documents

Syntheses of α- and β-C-glucopyranosyl serines from a common intermediate

(Chemical Equation Presented) A versatile synthesis leading to either C-linked α- or β-glucopyranosyl serines is presented from a common, advanced synthetic intermediate. Cyclization of the penultimate carbinol onto the alkene and methanolysis of the lactone yields selectively the α-linkage. A transposition of these last steps leads to the α-linked isomer selectively.