1072879-68-5

Basic information

• Product Name: (2R,3R)-cis-1-N-9-fluorenyl-2-carboxyethyl-3-phenylaziridine
• CAS NO: 1072879-68-5
• Molecular Weight: 355.436
• Mol File: 1072879-68-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3R)-cis-1-N-9-fluorenyl-2-carboxyethyl-3-phenylaziridine(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R)-cis-1-N-9-fluorenyl-2-carboxyethyl-3-phenylaziridine(1072879-68-5)
• EPA Substance Registry System: (2R,3R)-cis-1-N-9-fluorenyl-2-carboxyethyl-3-phenylaziridine(1072879-68-5)

Safety Data

• Hazardous Substances Data: 1072879-68-5(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 81532-35-6 N-benzylidene-9H-fluoren-9-amine 

Relevant articles and documents

Mapping the active site in a chemzyme: Diversity in the N-substituent in the catalytic asymmetric aziridination of imines

(Chemical Equation Presented) The active site of the aziridination catalyst derived from either the VANOL or VAPOL ligand and B(OPh)3 is larger than expected and can accommodate not only significant substitution on the diarylmethyl unit of the imine but also that alkyl (but not perfluorylalkyl) substituents on the aryl groups lead to enhanced rates and enantioselection. The screen of diarylmethyl N-substituents on the imine revealed that the 3,5-di-tert-butyldianisylmethyl group (BUDAM) gave exceptionally high asymmetric inductions for imines of aryl aldehydes.