1073808-77-1Relevant articles and documents
Ruthenium hydride-catalyzed addition of aldehydes to dienes leading to β,γ-unsaturated ketones
Omura, Sohei,Fukuyama, Takahide,Horiguchi, Jiro,Murakami, Yuji,Ryu, Ilhyong
supporting information; experimental part, p. 14094 - 14095 (2009/03/11)
An efficient cross-addition reaction of dienes with aldehydes was developped by using RuHCl(CO)(PPh3)3 as a catalyst to give a wide variety of β,γ-unsaturated ketones, where a π-allylruthenium species, derived from hydroruthenation of diene, may be involved as a key intermediate. Copyright