107554-38-1

Basic information

• Product Name: (E)-2-(benzylideneamino)acetonitrile
• Synonyms: (E)-2-(benzylideneamino)acetonitrile
• CAS NO: 107554-38-1
• Molecular Weight: 144.176
• Mol File: 107554-38-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (E)-2-(benzylideneamino)acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(benzylideneamino)acetonitrile(107554-38-1)
• EPA Substance Registry System: (E)-2-(benzylideneamino)acetonitrile(107554-38-1)

Safety Data

• Hazardous Substances Data: 107554-38-1(Hazardous Substances Data)

Upstream product

• 151-63-3 cyanomethylamine sulfate 
• 100-52-7 benzaldehyde 
• 6011-14-9 2-aminoacetonitrile hydrochloride 
• 540-61-4 2-aminoacetonitrile 

Downstream Products

• 1233851-28-9 (1S,3R,3aS,6aR)-5-methyl-4,6-dioxo-3-phenyloctahydropyrro[3,4-c]pyrrole-1-carbonitrile 
• 1233850-92-4 (2S,3R,5R)-methyl 5-cyano-2-phenylpyrrolidine-3-carboxylate 
• 1233850-94-6 (2R,3S,5S)-methyl 5-cyano-2-phenylpyrrolidine-3-carboxylate 
• 1233851-14-3 (2S,3S,4S,5R)-dimethyl 2-cyano-5-phenylpyrrolidine-3,4-dicarboxylate 
• 1239880-83-1 C₁₃H₁₂N₂ 
• 102845-52-3 (3aS,4R,6aR)-2-Methyl-4-phenyl-4,6a-dihydro-3aH-pyrrolo[3,4-c]pyrrole-1,3-dione 
• 102845-60-3 methyl 2-phenylpyrrole-3-carboxylate 
• 102845-60-3 methyl 2-phenylpyrrole-3-carboxylate 
• 52179-69-8 methyl 2-phenyl-1H-pyrrole-3-carboxylate 
• 102845-54-5 (2R,3S,4S,5R)-2-Cyano-5-phenyl-pyrrolidine-3,4-dicarboxylic acid dimethyl ester 
• 102845-54-5 (2S,3S,4S,5R)-2-Cyano-5-phenyl-pyrrolidine-3,4-dicarboxylic acid dimethyl ester 
• 102845-56-7 (2S,3S)-5-Cyano-2-phenyl-pyrrolidine-3-carboxylic acid methyl ester 
• 102845-56-7 (2S,3R)-5-Cyano-2-phenyl-pyrrolidine-3-carboxylic acid methyl ester 
• 69994-52-1 dimethyl cis-5-phenyl-2-pyrroline-3,4-dicarboxylate 

Relevant articles and documents

Catalytic asymmetric 1,3-dipolar cycloaddition of α-iminonitriles

(Figure Presented) Improving the structural scope: A catalytic asymmetric 1,3-dipolar cycloaddition involving α-iminonitriles as azomethine precursors has been developed. In the presence of AgOAc/ Taniaphos as the catalyst system the reaction of α-iminonitriles with dimethyl fumarate and N-methyl maleimide affords 2-cyanopyrrolidines with good endo selectivity and enantioselectivity (68-≥99% ee; see scheme).

Process for preparing α-amino acid amides, α-amino acids and derivatives thereof

The invention relates to a process for preparing α-amino acid amides, the corresponding α-amino acids, or salt thereof, which are substituted at the β-site with at least one (hetero)aromatic group. This is achieved according to the invention by subjecting

Stereoselectivity of Cycloaddition of N-(Cyanomethyl)- and N-(α-Cyanobenzyl)imines with Olefinic Dipolarophiles. Synthetic Equivalents of Nitrile Ylide 1,3-Dipoles

N-(Cyanomethyl)- and N-(α-cyanobenzyl)imines derived from a variety of aldehydes and ketones can tautomerize into N-protonated azomethine ylides which undergo cycloadditions with olefinic dipolarophiles.These cycloadditions are often accompanied by the el