107557-46-0Relevant articles and documents
3-Acetyl-2,3-dihydro-2,2-dimethyloxazole; Synthesis, Properties and Its Application as Olefinic Partner in the Paterno-Buechi Reaction
Weuthen, Manfred,Scharf, Hans-Dieter,Runsink, Jan
, p. 1023 - 1026 (2007/10/02)
The preparation and properties of 3-acetyl-2,3-dihydro-2,2-dimethyloxazole (3) are described.The compound rearranges to 1-acetyl-2-methylpyrrole (8) on pyrolysis in presence of protons. 3 reacts with acetone and benzophenone photochemically under formation of both regioisomeric oxetanes 9,10 and 12, 13.The regioisomer 11 is the selective product in the case of acetophenone.