107751-31-5Relevant articles and documents
Novel iodine reagent system for regioselective cleavage of epoxides to alcohols
Telvekar, Vikas N.,Rane, Rajesh A.
, p. 2108 - 2112 (2010)
Epoxides are converted regioselectively to corresponding higher substituted alcohols with greater yields using diphosphorus tetraiodide (P 2I4) as a reducing agent and a catalytic amount of tetraethylammonium bromide at room temperature. Copyright Taylor & Francis Group, LLC.
New Zinc Catalyst for Hydrosilylation of Carbonyl Compounds
Alshakova, Iryna D.,Nikonov, Georgii I.
, p. 3305 - 3312 (2019/08/28)
A new zinc complex was synthesized and applied in the catalytic hydrosilylation of carbonyl compounds. Optimization of the reaction conditions showed that the presence a substoichiometric amount of methanol accelerates the process significantly. The reaction can proceed at very low catalyst load (down to 0.1 molpercent) under mild reaction conditions. The reaction tolerates the presence of C=C bonds, and thus can be useful for the synthesis of allylic alcohols from α,β-unsaturated aldehydes and ketones.
Chemoselective reduction of aldehydes and ketones by potassium diisobutyl-t-butoxy aluminum hydride (PDBBA)
Kim, Joo Yeon,Shin, Won Kyu,Jaladi, Ashok Kumar,An, Duk Keun
, p. 4236 - 4241 (2018/06/30)
t-Butoxy derivatives of DIBALH [lithium diisobutyl-t-butoxyaluminum hydride (LDBBA), sodium diisobutyl-t-butoxyaluminum hydride (SDBBA), and potassium diisobutyl-t-butoxyaluminum hydride (PDBBA)] were examined as chemoselective reducing agents of carbonyl compounds. Among them, PDBBA was found to be the most efficient for the reduction of aldehydes and ketones to the corresponding alcohols in the presence of ester, amide, and nitrile substituents at ambient temperature. In addition, the optimal conditions gave higher chemoselectivity for aldehydes in the presence of ketones.
