1078138-42-7

Basic information

• Product Name: 5,5-dimethyl-2-(1-phenylpropa-1,2-dien-1-yl)-1,3,2-dioxaphosphinane 2-oxide
• Synonyms: 5,5-dimethyl-2-(1-phenylpropa-1,2-dien-1-yl)-1,3,2-dioxaphosphinane 2-oxide
• CAS NO: 1078138-42-7
• Molecular Weight: 264.261
• Mol File: 1078138-42-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5,5-dimethyl-2-(1-phenylpropa-1,2-dien-1-yl)-1,3,2-dioxaphosphinane 2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5-dimethyl-2-(1-phenylpropa-1,2-dien-1-yl)-1,3,2-dioxaphosphinane 2-oxide(1078138-42-7)
• EPA Substance Registry System: 5,5-dimethyl-2-(1-phenylpropa-1,2-dien-1-yl)-1,3,2-dioxaphosphinane 2-oxide(1078138-42-7)

Safety Data

• Hazardous Substances Data: 1078138-42-7(Hazardous Substances Data)

Upstream product

• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 2428-06-0 2-chloro-5,5-dimethyl-[1,3,2]dioxaphosphinane 

Downstream Products

• 1093365-14-0 C₃₀H₃₇NO₃P₂ 
• 1078138-54-1 C₁₅H₁₈N₂O₃ 
• 1190078-60-4 C₁₉H₂₈O₆P₂ 
• 1204570-88-6 C₂₂H₂₃O₆P 
• 1204570-89-7 C₂₁H₂₁O₅P 
• 1263383-85-2 C₂₈H₂₇O₃P 
• 1263383-56-7 C₂₀H₂₃O₇P 
• 1263383-95-4 C₂₆H₂₉O₁₁P 
• 1263383-96-5 C₃₄H₄₀O₁₀P₂ 
• 1322669-10-2 C₂₃H₂₄NO₄P 
• 1322669-00-0 C₂₃H₂₃ClNO₄P 
• 1325449-67-9 C₁₉H₂₈O₅P₂S 
• 1325449-83-9 C₂₆H₂₈O₃P₂S 
• 1325449-74-8 C₂₆H₂₈O₄P₂ 

Relevant articles and documents

Highly functionalised (γ-azido/γ-fluoro-β-iodo/)vinyl derivatives from phosphorus based allenes or allenoates: I?O halogen bonding interactions

Multifunctional γ-azido/γ-fluoro-β-iodo-vinyl phosphine oxides/phosphonates/esters/sulfone were synthesised by iodination followed by azidation/fluorination of phosphorus-based allenes or allenoates (allenyl esters) or a sulphur based allene. Surprisingly, the reaction of (γ,β)-diiodo-vinyl-phosphonate with TBAF [n-Bu4NF] led to the corresponding allenylphosphonate; in contrast, the use of CsF in a similar reaction led to novel γ-diiodo-allenylphosphonate along with the corresponding non-halogenated allenylphosphonate. The combination AgF2/CuBr could be used to obtain the γ-fluoro-β-iodo-vinyl phosphine oxides and related phosphorus-free γ-fluoro-β-iodo-vinyl esters. In many cases, I?O halogen to oxygen non-covalent bonding interactions ('halogen bonding') involving the phosphoryl (PO) oxygen, as evidenced by single crystal X-ray crystallography, are also observed.