107866-10-4

Basic information

• Product Name: endo-1-acetoxy-6a-methyl-1,1a-dihydropropinden-6(6aH)-one
• Synonyms: endo-1-acetoxy-6a-methyl-1,1a-dihydropropinden-6(6aH)-one
• CAS NO: 107866-10-4
• Molecular Weight: 216.236
• Mol File: 107866-10-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: endo-1-acetoxy-6a-methyl-1,1a-dihydropropinden-6(6aH)-one(CAS DataBase Reference)
• NIST Chemistry Reference: endo-1-acetoxy-6a-methyl-1,1a-dihydropropinden-6(6aH)-one(107866-10-4)
• EPA Substance Registry System: endo-1-acetoxy-6a-methyl-1,1a-dihydropropinden-6(6aH)-one(107866-10-4)

Upstream product

• 76274-21-0 2-acetoxy-2-methylnaphthalen-1(2H)-one 

Downstream Products

• 7469-77-4 2-methylnaphthalen-1-ol 
• 13247-45-5 4-acetyl-2-methylnaphthalene-1,3-diol 
• 107866-09-1 3-acetoxy-2-methyl-1-naphthol 
• 76274-21-0 2-acetoxy-2-methylnaphthalen-1(2H)-one 

Relevant articles and documents

The Photochemistry of 2-Acetoxynaphthalen-1(2H)-ones

The photochemistry of the 2-acetoxynaphthalen-1(2H)-ones (4), (13), (20), and (26) has been examined.In each case there was rapid formation of a mixture of products, which arose either by homolytic dissociation of the C-OAc bond of by rearrangement involving acetoxy group migration.Two types of rearrangement were observed.The first involved 1,2-acetoxy group with C(2)-C(4) bond formation to give the dihydrocyclopropindenones (7), (15), (22), and (28).This reaction, which is stereospecific, yields the endo-6-acetoxy isomer only, and it is thought to proceed by a concerted non-ionic pathway.The second rearrangement, which is believed to have an ionic mechanism, resulted in formation of 3-acetoxynaphthols from naphthalenones (4) and (26), and 4-acetoxynaphthols form naphthalenones (13) and (20), in which the 3-position is substituted.