1078738-57-4

Basic information

• Product Name: 4-methoxy-2,3,5,6-tetrafluorophenylcopper-phenanthroline complex
• Synonyms: 4-methoxy-2,3,5,6-tetrafluorophenylcopper-phenanthroline complex
• CAS NO: 1078738-57-4
• Molecular Weight: 422.849
• Mol File: 1078738-57-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-methoxy-2,3,5,6-tetrafluorophenylcopper-phenanthroline complex(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-2,3,5,6-tetrafluorophenylcopper-phenanthroline complex(1078738-57-4)
• EPA Substance Registry System: 4-methoxy-2,3,5,6-tetrafluorophenylcopper-phenanthroline complex(1078738-57-4)

Safety Data

• Hazardous Substances Data: 1078738-57-4(Hazardous Substances Data)

Upstream product

• 66-71-7 1,10-Phenanthroline 
• 2324-98-3 2,3,5,6-tetrafluoroanisole 

Relevant articles and documents

A general method for copper-catalyzed arylation of arene C-H bonds

A general method for copper-catalyzed arylation of sp2 C-H bonds with pKa's below 35 has been developed. The method employs aryl halide as the coupling partner, lithium alkoxide or K3PO4 base, and DMF, DMPU, or mixed DMF/xylenes solvent. A variety of electron-rich and electron-poor heterocycles such as azoles, caffeine, thiophenes, benzofuran, pyridine oxides, pyridazine, and pyrimidine can be arylated. Furthermore, electron-poor arenes possessing at least two electron-withdrawing groups on a benzene ring can also be arylated. Two arylcopper-phenanthroline complex intermediates were independently synthesized.