107932-09-2Relevant articles and documents
1,1-DICHLORO-2,2,2-TRIFLUOROETHYL ZINC AND LITHIUM COMPOUNDS IN ASYMMETRIC SYNTHESIS
Solladie-Cavallo, A.,Quazzotti, S.
, p. 221 - 228 (1990)
Addition of 1,1-dichloro-2,2,2-trifluoroethyl zinc chloride 2 complexed with optically pure ligands leads to zero percentage of asymmetric induction due to too large a distance between the chiral centers involved.However, addition of 2 and of the correspo
EFFICIENT CARBON-CARBON BOND FORMATION WITH THERMALLY STABLE 1,1-DIHALO-2,2,2-TRIFLUOROETHYLZINC REAGENT
Fujita, Makoto,Morita, Tomoe,Hiyama, Tamejiro
, p. 2135 - 2138 (2007/10/02)
The zinc carbenoids CF3CX2ZnX, prepared from CF3CX3 and zinc powder in dimethylformamide, were found thermally stable to add to aldehyde carbonyls in excellent yields.