107960-33-8

Basic information

• Product Name: 2-methyl-α-hydroxyiminobenzeneacetonitrile
• Synonyms: 2-methyl-α-hydroxyiminobenzeneacetonitrile
• CAS NO: 107960-33-8
• Molecular Weight: 160.175
• Mol File: 107960-33-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-methyl-α-hydroxyiminobenzeneacetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-α-hydroxyiminobenzeneacetonitrile(107960-33-8)
• EPA Substance Registry System: 2-methyl-α-hydroxyiminobenzeneacetonitrile(107960-33-8)

Safety Data

• Hazardous Substances Data: 107960-33-8(Hazardous Substances Data)

Upstream product

• 1940-57-4 9H-fluoren-9-yl bromide 
• 107960-26-9 C₉H₇N₂O₂^(1-)*Ag⁽¹⁺⁾ 
• 22364-68-7 2-tolylmethylnitrile 

Downstream Products

• 133409-72-0 methyl (E)-2-[2-(bromomethyl)phenyl]-2-(methoxyimino)acetate 
• 120974-97-2 methyl-(E)-2-(2-tolyl)-2-methoxyiminoacetate 
• 143390-89-0 methyl (E)-2-methoxyimino-2-[2-(o-tolyloxymethyl)phenyl]acetate 
• 156581-21-4 (E)-2-methyl-α-methoxyiminophenylacetonitrile 
• 159731-22-3 (Z)-2-methyl-α-methoxyiminophenylacetonitrile 
• 52042-86-1 C₁₇H₁₁Cl₃FN₃O₂S 
• 52042-89-4 C₁₇H₁₂Cl₂FN₃O₂S 

Relevant articles and documents

Green synthetic method of kresoxim-methyl

The invention belongs to the technical field of fine chemical engineering, and particularly relates to a green synthetic method of kresoxim-methyl. The method comprises the following steps: carrying out nitrous nitrification by using 2-methylbenzyl cyanide as an initial raw material, carrying out methylation, carrying out hydrolytic methylation or hydrolytic esterification, carrying out bromination and carrying out an etherification reaction to obtain the high-content kresoxim-methyl. The method provided by the invention has a short reaction period, a high conversion rate, and excellent product quality, changes the defect that high-concentration hydrochloric acid gas is used for preparation in a traditional process, and has the advantages of simple operation steps, simple equipment, low energy consumption, a short period, high productivity and environmental protection.

Reaction of the Silver Salts of Arylnitroacetonitriles with 9-Bromofluorene. Synthesis of 9-(α-Cyanoarylidene)fluorenes

The silver salts 1a-d react with 9-bromofluorene to give both C- and O-alkylated products 2 and 3.The latter decompose to yield 9-fluorenone and the α-cyanooximes 5.The products 2 upon treatment with NaOH/EtOH eliminate HNO2 to afford 9-(α-cyanoarylidene)fluorenes 4 in 80percent yield. 9-Chloro-9-phenylfluorene reacts with salt 1a to give only C-alkylated product 6 in 70percent yield.