108011-64-9

Basic information

• Product Name: 3-(p-tolyl)cycloheptanone
• Synonyms: 3-(p-tolyl)cycloheptanone
• CAS NO: 108011-64-9
• Molecular Weight: 202.296
• Mol File: 108011-64-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(p-tolyl)cycloheptanone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(p-tolyl)cycloheptanone(108011-64-9)
• EPA Substance Registry System: 3-(p-tolyl)cycloheptanone(108011-64-9)

Safety Data

• Hazardous Substances Data: 108011-64-9(Hazardous Substances Data)

Upstream product

• 615-53-2 ethyl N-methyl-N-nitrosocarbamate 
• 52776-14-4 2-(4-methylphenyl)cyclohexanone 
• 33604-67-0 (4-methylphenyl)azo 4-methylphenyl sulfone 
• 1121-66-0 2-Cyclohepten-1-one 

Relevant articles and documents

REACTIONS OF ARYLAZO ARYL SULFONES WITH α,β-UNSATURATED ESTERS AND KETONES CATALYZED BY PALLADIUM(0) COMPLEX

The palladium(0) catalyzed reactions of arylazo aryl sulfones (1) with α,β-unsaturated esters in benzene give aryl-substituted esters as major products and hydroarylated esters as minor products.The reactions of 1 with acyclic α,β-unsaturated ketones give considerable amounts of hydroarylated ketones and aryl-substituted ketones under similar conditions, whereas the reactions of 1 with cyclic α,β-unsaturated ketones afforded selectively hydroarylated compounds and no formation of aryl-substituted ketones was found.A plausible reaction mechanism is proposed.Key words: Arylazo aryl sulfones; palladium(0) catalyst; arylation; α,β-unsaturated carbonyl compounds; diarylpalladiumII) intermediate; catalytic cycle.