108025-34-9Relevant articles and documents
Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
Zhang, Liangliang,Oestreich, Martin
, p. 8061 - 8063 (2019/01/14)
A silylation of vinyliodonium salts using zinc-based silicon reagents as nucleophiles is reported. This cross-coupling is catalyzed by copper, and vinylsilanes are obtained in high yield likely following a Cu(I)/Cu(III) reaction mechanism. The procedure i
Addition reactions of lithiodimethylphenylsilane to (η4-1,3-diene)-Fe(CO)3 and (η6-arene)Cr(CO)3 complexes
Yeh, Ming-Chang P.,Sheu, Peng-Yu,Ho, Jin-Xuan,Chiang, Yi-Lin,Chiu, Dai-Yu,Narasimha Rao
, p. 13 - 20 (2007/10/03)
Treatments of (η4-cyclohexa-1,3-diene)Fe(CO)3 complex with 1.2 equivalents of PhMe2SiLi, followed by quenching the reactive intermediate with CF3COOH generated 1-dimethyl(phenyl)silylcyclohex-1-ene and with 2-(p
ORGANIC SYNTHESIS WITH REAGENTS DERIVED FROM 3R3SiMgMe AND MnCl2
Fugami, Keigo,Hibino, Jun-ichi,Nakatsukasa, Shigeki,Matsubara, Seijiro,Oshima, Koichiro,et al.
, p. 4277 - 4292 (2007/10/02)
Synthetically useful reactions mediated by reagents derived from 3 equiv. of R3SiMgMe and MnCl2 are disclosed. (1) The manganese species reacted with terminal acetylenes to give 1,2-disilylated 1-alkenes.Mono- and bis(trimethylsilyl)acetylenes gave tri- a