108182-78-1

Basic information

• Product Name: (2R,3R)-3-((3aR,4S,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2,3-dihydroxy-propionic acid methyl ester
• CAS NO: 108182-78-1
• Molecular Weight: 368.384
• Mol File: 108182-78-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,3R)-3-((3aR,4S,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2,3-dihydroxy-propionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R)-3-((3aR,4S,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2,3-dihydroxy-propionic acid methyl ester(108182-78-1)
• EPA Substance Registry System: (2R,3R)-3-((3aR,4S,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2,3-dihydroxy-propionic acid methyl ester(108182-78-1)

Safety Data

• Hazardous Substances Data: 108182-78-1(Hazardous Substances Data)

Upstream product

• 102919-04-0 benzyl 2,3-O-isopropylidene-α-D-lyxo-pentodialdo-1,4-furanoside 
• 74912-02-0 1-O-benzyl-2,3-O-isopropylidene-α-D-manno-furanose 
• 108182-77-0 methyl uronate 

Downstream Products

• 105592-33-4 benzyl 2,3-O-isopropylidene-α-D-glycero-D-manno-heptofuranoside 
• 105592-34-5 benzyl 2,3-O-isopropylidene-β-L-glycero-L-gulo-heptofuranoside 

Relevant articles and documents

ON THE STEREOCHEMISTRY OF OSMIUM TETRAOXIDE OXIDATIONS OF ALLYLIC SYSTEMS USED IN THE SYNTHESIS OF HIGHER-CARBON SUGARS

The stereochemistry of the major osmylation products of carbohydrate-based allylic alcohols can usually be predicted by application of Kishi's empirical rule.In particular, the addition of OsO4 can be formulated as taking place in the more abundant conformation on the surface anti to a pyranose or furanose ring-oxygen atom located at a stereocentre adjacent to the olefinic linkage.Exceptions to Kishi's empirical rule for osmylation are sometimes encountered with conjugated carbonyl compounds.