108303-98-6Relevant articles and documents
Chiral Nanoparticles/Lewis Acids as Cooperative Catalysts for Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Amides
Yasukawa, Tomohiro,Saito, Yuuki,Miyamura, Hiroyuki,Kobayashi, Shū
, (2016)
Cooperative catalysts consisting of chiral Rh/Ag nanoparticles and Sc(OTf)3have been developed that catalyze asymmetric 1,4-addition reactions of arylboronic acids with α,β-unsaturated amides efficiently. The reaction has been considered one of
Rhodium-catalyzed domino conjugate addition-cyclization reactions for the synthesis of a variety of N- and O-heterocycles: Arylboroxines as effective carbon nucleophiles
Park, Ja Ock,Youn, So Won
supporting information; experimental part, p. 2258 - 2261 (2010/07/17)
Facile and efficient Rh(I)-catalyzed domino conjugate addition-cyclization reactions of olefins bearing two electrophilic sites and a pendant nucleophile with organoboroxines have been developed to afford a variety of N- and O-heterocycles, such as 3,4-dihydroquinolin-2(1H)-ones, 3,4-dihydrocoumarins, and pyrrolidin-2-ones, which constitute important motifs in biologically active natural and synthetic organic compounds.
Rhodium(I)-catalysed hydrocarbonylation and silylcarbonylation reactions of alkynes in the presence of primary amines leading to 2-pyrrolidinones and 4-silylated 1-aza-1,3-butadienes
Baerfacker, Lars,Hollmann, Christoph,Eilbracht, Peter
, p. 4493 - 4506 (2007/10/03)
Rh(I)-catalysed hydrocarbonylation of alkynes 1 in the presence of primary amines gives substituted 2-pyrrolidinones 3 in a one-pot procedure. Replacement of hydrogen by hydrosilanes via silylcarbonylation leads to 4- silylated l-aza-l,3-butadienes 5. The
