108362-43-2

Basic information

• Product Name: 3-methyl-3-phenylthiohex-5-yn-2-one
• Synonyms: 3-methyl-3-phenylthiohex-5-yn-2-one
• CAS NO: 108362-43-2
• Molecular Weight: 218.32
• Mol File: 108362-43-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-methyl-3-phenylthiohex-5-yn-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-3-phenylthiohex-5-yn-2-one(108362-43-2)
• EPA Substance Registry System: 3-methyl-3-phenylthiohex-5-yn-2-one(108362-43-2)

Safety Data

• Hazardous Substances Data: 108362-43-2(Hazardous Substances Data)

Upstream product

• 13023-53-5 3-phenylsulfanyl-butan-2-one 
• 659-86-9 propargyl iodide 

Downstream Products

• 108378-33-2 4-methyl-5-phenylthiohex-3-en-2-one 
• 108378-34-3 4-methyl-5-phenylthiohex-3-en-2-one 
• 108378-31-0 3-methyl-3-phenylthiohex-5-yn-2-ol formate 
• 108378-32-1 4-methyl-5-phenylthiohex-3-en-1-yne 
• 108378-29-6 3-methyl-3-phenylthiohex-5-yn-2-ol 

Relevant articles and documents

Rearrangements of 2-Phenylthioethanols with Alkenyl, Alkynyl, Ester, and Other Functionalised Alkyl Substituents at the Migration Origin: Synthesis of γ-Phenylthiocrotonate Esters

The effects of functional groups near the migration origin in and PhS shifts are explored: an α-CO2R group prevents migration, α or β vinyl groups have only steric effects, alkynyl or CO2Et groups encourage rearrangement and provide routes to γ-phenylthio unsaturated esters and ketones.