108385-63-3

Basic information

• Product Name: (4R,5S)-4-Methyl-3-(4-methyl-pent-3-enoyl)-5-phenyl-oxazolidin-2-one
• Synonyms: (4R,5S)-4-Methyl-3-(4-methyl-pent-3-enoyl)-5-phenyl-oxazolidin-2-one
• CAS NO: 108385-63-3
• Molecular Weight: 273.332
• Mol File: 108385-63-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R,5S)-4-Methyl-3-(4-methyl-pent-3-enoyl)-5-phenyl-oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5S)-4-Methyl-3-(4-methyl-pent-3-enoyl)-5-phenyl-oxazolidin-2-one(108385-63-3)
• EPA Substance Registry System: (4R,5S)-4-Methyl-3-(4-methyl-pent-3-enoyl)-5-phenyl-oxazolidin-2-one(108385-63-3)

Safety Data

• Hazardous Substances Data: 108385-63-3(Hazardous Substances Data)

Upstream product

• 504-85-8 4-methyl-pent-3-enoic acid 
• 77943-39-6 4-methyl-5-phenyloxazolidin-2-one 
• 41199-96-6 4-methyl-3-pentenoic acid chloride 

Downstream Products

• 109687-77-6 2-methyl-4(R)-(phenylmethyl)-5-<(2-tetrahydropyranyl)oxy>-2-pentene 
• 109687-76-5 4-methyl-2(R)-(phenylmethyl)-3-penten-1-ol 
• 77943-39-6 4-methyl-5-phenyloxazolidin-2-one 
• 109687-75-4 (4R,5S)-3-((S)-2-Benzyl-4-methyl-pent-3-enoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 109687-75-4 (4R,5S)-3-((R)-2-Benzyl-4-methyl-pent-3-enoyl)-4-methyl-5-phenyl-oxazolidin-2-one 

Relevant articles and documents

New Approaches to the Synthesis of trans-Alkene Isosteres of Dipeptides

Two new syntheses of protected dipeptide analogues bearing a trans carbon-carbon double bond in place of the amide linkage are reported.One route is a linear synthesis employing the rearrangement of an allylic selenide to a protected allylic amine.The second route is convergent and uses the Julia olefin synthesis in a key step.The latter route is fully stereocontrolled and has been used to prepare protected trans-alkene isosteres of the dipeptides TyrAla, PhePhe, LeuPhe, and LeuLeu.